Exam 15: Dienes and Aromaticity

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Which compound or ion has five molecular orbitals? Which compound or ion has five <font face=symbol></font> molecular orbitals?

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Cyclooctatetraene (COT) has eight pi electrons but is a stable compound. Explain why. Cyclooctatetraene (COT) has eight pi electrons but is a stable compound. Explain why.

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Which compound should have the greatest max in its UV spectrum? Which compound should have the greatest <font face=symbol></font><sub>max</sub> in its UV spectrum?

(Multiple Choice)
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1,3-Butadiene, the simplest conjugated diene, has a UV absorption at 217 nm. (One nanometer = 10-9 meter.) a. Calculate the energy of UV radiation with this wavelength (in kJ mol-1). Show your work. b. Shown is an MO electron-occupancy diagram for the molecular orbitals of 1,3-butadiene. Draw an arrow on this diagram that corresponds to the energy of this UV radiation. 1,3-Butadiene, the simplest conjugated diene, has a UV absorption at 217 nm. (One nanometer = 10<sup>-9</sup> meter.) a. Calculate the energy of UV radiation with this wavelength (in kJ mol<sup>-1</sup>). Show your work. b. Shown is an MO electron-occupancy diagram for the <font face=symbol></font> molecular orbitals of 1,3-butadiene. Draw an arrow on this diagram that corresponds to the energy of this UV radiation.

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Which compound has the smaller (less positive or more negative) heat of formation? Which compound has the smaller (less positive or more negative) heat of formation?

(Multiple Choice)
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